Issue 24, 2010

Autonomous viscosity oscillation by reversible complex formation of terpyridine-terminated poly(ethylene glycol) in the BZ reaction

Abstract

Autonomous viscosity oscillation by the reversible complex formation of terpyridine-terminated PEG and/or terpyridine-terminated TetraPEG in the BZ reaction was achieved. The BZ reaction induces the periodical binding/dissociation of the Ru–terpyridine complex and causes periodical molecular changes to result in viscosity changes.

Graphical abstract: Autonomous viscosity oscillation by reversible complex formation of terpyridine-terminated poly(ethylene glycol) in the BZ reaction

Supplementary files

Article information

Article type
Communication
Submitted
07 Aug 2010
Accepted
05 Oct 2010
First published
19 Oct 2010

Soft Matter, 2010,6, 6072-6074

Autonomous viscosity oscillation by reversible complex formation of terpyridine-terminated poly(ethylene glycol) in the BZ reaction

T. Ueno, K. Bundo, Y. Akagi, T. Sakai and R. Yoshida, Soft Matter, 2010, 6, 6072 DOI: 10.1039/C0SM00788A

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