Issue 17, 2011
From the journal:

Chemical Communications

A multipurpose gold(i) precatalyst†

Mihai Raducan,a   Carles Rodríguez-Escrich,a   Xacobe C. Cambeiro,a   Eduardo C. Escudero-Adán,a   Miquel A. Pericàs*ab  and  Antonio M. Echavarren*ac  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain
E-mail: mapericas@iciq.es, aechavarren@iciq.es

b Departament de Química Orgànica, Universitat de Barcelona, 08028 Barcelona, Spain

c Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, C/Marcel·li Domingo s/n, 43007 Tarragona, Spain

Abstract

[Au(tmbn)2](SbF6) is the first gold(I) complex supported by two nitrile ligands that is indefinitely stable at room temperature. This is a highly versatile precatalyst that can be used for the preparation of active and robust solid-supported gold(I) catalysts.

Graphical abstract: A multipurpose gold(i) precatalyst

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Article information

DOI
https://doi.org/10.1039/C1CC10293A
Article type
Communication
Submitted
16 Jan 2011
Accepted
02 Mar 2011
First published
23 Mar 2011

Chem. Commun., 2011,47, 4893-4895

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A multipurpose gold(I) precatalyst

M. Raducan, C. Rodríguez-Escrich, X. C. Cambeiro, E. C. Escudero-Adán, M. A. Pericàs and A. M. Echavarren, Chem. Commun., 2011, 47, 4893 DOI: 10.1039/C1CC10293A

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