Issue 23, 2011
From the journal:

Chemical Communications

Stereochemistry of electrophilic attack at 34e− dimetallic complexes: the case of diiron dithiolato carbonyls + MeS+†

Matthew T. Olsen,a   Danielle L. Gray,a   Thomas B. Rauchfuss,*a   Luca De Gioiab  and  Giuseppe Zampella*b  

* Corresponding authors

a Department of Chemistry, University of Illinois, Urbana, USA
E-mail: rauchfuz@uiuc.edu

b Department of Biotechnology and Biosciences, University of Milano-Bicocca, Piazza della Scienza 2, 20126-Milan, Italy
E-mail: giuseppe.zampella@unimib.it

Abstract

Experimental and computational experiments show that the electrophile MeS+ attacks a single Fe center in Fe2(propanedithiolate)(CO)4(PMe3)2 followed by isomerization of this terminal thiolato complex to the corresponding μ-SMe derivative.

Graphical abstract: Stereochemistry of electrophilic attack at 34e− dimetallic complexes: the case of diiron dithiolato carbonyls + MeS+

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC10858A
Article type
Communication
Submitted
14 Feb 2011
Accepted
19 Mar 2011
First published
04 Apr 2011

Chem. Commun., 2011,47, 6554-6556

Permissions

Request permissions

Stereochemistry of electrophilic attack at 34e− dimetallic complexes: the case of diiron dithiolato carbonyls + MeS+

M. T. Olsen, D. L. Gray, T. B. Rauchfuss, L. D. Gioia and G. Zampella, Chem. Commun., 2011, 47, 6554 DOI: 10.1039/C1CC10858A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements