Issue 18, 2011

PdCl2-catalyzed efficient allylation and benzylation of heteroarenes under ligand, base/acid, and additive-free conditions

Abstract

We present a PdCl2-catalyzed protocol for highly efficient allylation and benzylation of a rich variety of N-, O-, and S-containing heteroarenes under base/acid, additive, and ligand-free conditions. The method represents the very few examples for simple, universally applicable, clean, and atom-efficient functionalization of heteroarenes.

Graphical abstract: PdCl2-catalyzed efficient allylation and benzylation of heteroarenes under ligand, base/acid, and additive-free conditions

Supplementary files

Article information

Article type
Communication
Submitted
18 Feb 2011
Accepted
14 Mar 2011
First published
31 Mar 2011

Chem. Commun., 2011,47, 5289-5291

PdCl2-catalyzed efficient allylation and benzylation of heteroarenes under ligand, base/acid, and additive-free conditions

F. Yuan, L. Gao and F. Han, Chem. Commun., 2011, 47, 5289 DOI: 10.1039/C1CC10953G

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