Issue 18, 2011
From the journal:

Chemical Communications

Methyl modified MOF-5: a water stable hydrogen storage material†

Jie Yang,a   Anna Grzech,b   Fokko M. Mulderb  and  Theo J. Dingemans*a  

* Corresponding authors

a Faculty of Aerospace Engineering, Delft University of Technology, Kluyverweg 1, Delft, The Netherlands
E-mail: t.j.dingemans@tudelft.nl
Fax: +31 (0)152784472
Tel: +31 (0)152784520

b Department of Radiation, Radionuclides and Reactors, Faculty of Applied Sciences, Delft University of Technology, Mekelweg 15, 2629 JB Delft, The Netherlands
E-mail: f.m.mulder@tudelft.nl
Fax: +31 (0)152783803
Tel: +31 (0)152784870

Abstract

Water stable methyl modified MOF-5s have been synthesized via a solvothermal route. Methyl- and 2,5-dimethyl-modified MOF-5s show the same topology and hydrogen uptake capability as that of MOF-5. The H2 uptake capacity of MOF-5, however, drops rapidly when exposed to the ambient air, whereas the H2 uptake capacities of the methyl modified MOF-5s remain stable for 4 days.

Graphical abstract: Methyl modified MOF-5: a water stable hydrogen storage material

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Article information

DOI
https://doi.org/10.1039/C1CC11054C
Article type
Communication
Submitted
22 Feb 2011
Accepted
18 Mar 2011
First published
30 Mar 2011

Chem. Commun., 2011,47, 5244-5246

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Methyl modified MOF-5: a water stable hydrogen storage material

J. Yang, A. Grzech, F. M. Mulder and T. J. Dingemans, Chem. Commun., 2011, 47, 5244 DOI: 10.1039/C1CC11054C

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