Issue 25, 2011

Lewis acid-activated oxidation of alcohols by permanganate

Abstract

The oxidation of alcohols by KMnO4 is greatly accelerated by various Lewis acids. Notably the rate is increased by 4 orders of magnitude in the presence of Ca2+. The mechanisms of the oxidation of CH3OH and PhCH(OH)CH3 by MnO4 and BF3·MnO4 have also been studied computationally by the DFT method.

Graphical abstract: Lewis acid-activated oxidation of alcohols by permanganate

Supplementary files

Article information

Article type
Communication
Submitted
09 Apr 2011
Accepted
04 May 2011
First published
25 May 2011

Chem. Commun., 2011,47, 7143-7145

Lewis acid-activated oxidation of alcohols by permanganate

H. Du, P. Lo, Z. Hu, H. Liang, K. Lau, Y. Wang, W. W. Y. Lam and T. Lau, Chem. Commun., 2011, 47, 7143 DOI: 10.1039/C1CC12024G

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