Stability improvement of Cu3(BTC)2 metal–organic frameworks under steaming conditions by encapsulation of a Keggin polyoxometalate

Danilo Mustafa; Eric Breynaert; Sneha R. Bajpe; Johan A. Martens; Christine E. A. Kirschhock

doi:10.1039/C1CC12341F

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Stability improvement of Cu₃(BTC)₂ metal–organic frameworks under steaming conditions by encapsulation of a Keggin polyoxometalate†

Danilo Mustafa,^a Eric Breynaert,*^a Sneha R. Bajpe,^a Johan A. Martens^a and Christine E. A. Kirschhock^a

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* Corresponding authors

^a Center for Surface Chemistry and Catalysis, Department of Microbial and Molecular Systems, KU Leuven, Belgium
E-mail: Eric.Breynaert@biw.kuleuven.be
Fax: +32 16 321998
Tel: +32 16 321598

Abstract

Cu₃(BTC)₂ with an incorporated Keggin polyoxometalate was demonstrated to be stable under steaming conditions up to 483 K, while the isostructural HKUST-1 degrades and transforms into [Cu₂OH(BTC)(H₂O)]_n·2nH₂O from 343 K onwards.

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Article information

DOI: https://doi.org/10.1039/C1CC12341F
Article type: Communication
Submitted: 21 Apr 2011
Accepted: 31 May 2011
First published: 15 Jun 2011

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Chem. Commun., 2011,47, 8037-8039

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Stability improvement of Cu₃(BTC)₂ metal–organic frameworks under steaming conditions by encapsulation of a Keggin polyoxometalate

D. Mustafa, E. Breynaert, S. R. Bajpe, J. A. Martens and C. E. A. Kirschhock, Chem. Commun., 2011, 47, 8037 DOI: 10.1039/C1CC12341F

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