Issue 29, 2011

Addition of a cyclopropyl alkyne to tetramesityldigermene: evidence for a biradical intermediate

Abstract

The reaction pathway for the addition of alkynes to tetramesityldigermene was examined using a cyclopropyl alkyne mechanistic probe. The results obtained indicate that the reaction is stepwise and involves biradical intermediates.

Graphical abstract: Addition of a cyclopropyl alkyne to tetramesityldigermene: evidence for a biradical intermediate

Supplementary files

Article information

Article type
Communication
Submitted
03 May 2011
Accepted
01 Jun 2011
First published
23 Jun 2011

Chem. Commun., 2011,47, 8382-8384

Addition of a cyclopropyl alkyne to tetramesityldigermene: evidence for a biradical intermediate

K. L. Hurni and K. M. Baines, Chem. Commun., 2011, 47, 8382 DOI: 10.1039/C1CC12600H

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