Calix[4]arene-supported FeIII2LnIII2 clusters

Sergio Sanz; Kerry Ferreira; Ruaraidh D. McIntosh; Scott J. Dalgarno; Euan K. Brechin

doi:10.1039/C1CC13055B

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Calix[4]arene-supported Fe^III₂Ln^III₂ clusters†

Sergio Sanz,^a Kerry Ferreira,^b Ruaraidh D. McIntosh,^b Scott J. Dalgarno*^b and Euan K. Brechin*^a

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* Corresponding authors

^a EaStCHEM School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, Scotland
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: +44 (0)131 650 6453
Tel: +44 (0)131 650 7545

^b School of Engineering and Physical Sciences – Chemistry, Heriot – Watt University, Riccarton, Edinburgh, Scotland
E-mail: S.J.Dalgarno@hw.ac.uk
Fax: +44(0) 131 451 3180
Tel: +44 (0)131 451 8025

Abstract

A series of Fe^III₂Ln^III₂ clusters have been synthesised under facile bench top conditions. The resulting clusters pack in a manner akin to the calixarene solvate, and represent an important entry point to this new type of 3d–4f system.

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Article information

DOI: https://doi.org/10.1039/C1CC13055B
Article type: Communication
Submitted: 24 May 2011
Accepted: 29 Jun 2011
First published: 18 Jul 2011

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Chem. Commun., 2011,47, 9042-9044

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Calix[4]arene-supported Fe^III₂Ln^III₂ clusters

S. Sanz, K. Ferreira, R. D. McIntosh, S. J. Dalgarno and E. K. Brechin, Chem. Commun., 2011, 47, 9042 DOI: 10.1039/C1CC13055B

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