Issue 37, 2011

Retention of palladium and phosphine ligands using nanoporous polydicyclopentadiene thimbles

Abstract

Thimbles composed of polydicyclopentadiene retained Pd and phosphines used in Buchwald–Hartwig and Sonogashira coupling reactions but allowed the products to permeate. The products were isolated in high yields on the exteriors of the thimbles with no detectable contamination from phosphine and with Pd loadings as low as < 5.5 ppm.

Graphical abstract: Retention of palladium and phosphine ligands using nanoporous polydicyclopentadiene thimbles

Supplementary files

Article information

Article type
Communication
Submitted
31 May 2011
Accepted
01 Aug 2011
First published
22 Aug 2011

Chem. Commun., 2011,47, 10236-10238

Retention of palladium and phosphine ligands using nanoporous polydicyclopentadiene thimbles

A. Gupta, T. R. Long, D. G. Rethwisch and N. B. Bowden, Chem. Commun., 2011, 47, 10236 DOI: 10.1039/C1CC13221K

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