Issue 39, 2011
From the journal:

Chemical Communications

Homoleptic tris(methoxydimethylsilyl)silanides of the alkaline earth metals: first zwitterionic silanides with two naked silyl anions†‡§

Bryan Carlson,a   Adelia J. A. Aquino,a   Louisa J. Hope-Weeks,a   Bruce Whittlesey,a   Brian McNerney,a   William L. Hasea  and  Clemens Krempner*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Texas Tech University, Memorial Dr & Boston, Lubbock, TX, USA
E-mail: clemens.krempner@ttu.edu
Fax: +1 806-742-1289
Tel: +1 806-742-3064

Abstract

The first zwitterionic alkaline earth metal silanides featuring two naked silyl anions were synthesized and a combined structural and computational study on these zwitterions revealed a correlation between the energy of the HOMO and the degree of negative charge of the naked silyl anions.

Graphical abstract: Homoleptic tris(methoxydimethylsilyl)silanides of the alkaline earth metals: first zwitterionic silanides with two naked silyl anions

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DOI
https://doi.org/10.1039/C1CC13933A
Article type
Communication
Submitted
01 Jul 2011
Accepted
17 Aug 2011
First published
05 Sep 2011

Chem. Commun., 2011,47, 11089-11091

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Homoleptic tris(methoxydimethylsilyl)silanides of the alkaline earth metals: first zwitterionic silanides with two naked silyl anions

B. Carlson, A. J. A. Aquino, L. J. Hope-Weeks, B. Whittlesey, B. McNerney, W. L. Hase and C. Krempner, Chem. Commun., 2011, 47, 11089 DOI: 10.1039/C1CC13933A

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