Issue 43, 2011

A chiral tetragonal magnesium-carboxylate framework with nanotubular channels

Abstract

Reported here is a rare example of a highly symmetrical chiral Mg-based MOF (CPF-1) with nanotubular channels, built from 41 (or 43) helical chains. It exhibits a high gas sorption capacity (ca. 1.29 wt% H2 at 77 K, 1 atm; 84 cm3 g−1 of CO2 at 273 K, 1 atm).

Graphical abstract: A chiral tetragonal magnesium-carboxylate framework with nanotubular channels

Supplementary files

Article information

Article type
Communication
Submitted
05 Aug 2011
Accepted
29 Sep 2011
First published
07 Oct 2011

Chem. Commun., 2011,47, 11852-11854

A chiral tetragonal magnesium-carboxylate framework with nanotubular channels

Q. Lin, T. Wu, S. Zheng, X. Bu and P. Feng, Chem. Commun., 2011, 47, 11852 DOI: 10.1039/C1CC14836B

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