Issue 40, 2011

9-H-9-Borafluorene dimethyl sulfide adduct: a product of a unique ring-contraction reaction and a useful hydroboration reagent

Abstract

The dimethyl sulfide adduct 2(DMS) is a crystalline storage form of the unstable hydroboration reagent 9-H-9-borafluorene (2); 2(DMS) is available by the addition of DMS to either in situ generated [2]2 or 1,2-(2,2′-biphenylylene)diborane(6) (7).

Graphical abstract: 9-H-9-Borafluorene dimethyl sulfide adduct: a product of a unique ring-contraction reaction and a useful hydroboration reagent

Supplementary files

Article information

Article type
Communication
Submitted
08 Aug 2011
Accepted
23 Aug 2011
First published
06 Sep 2011

Chem. Commun., 2011,47, 11339-11341

9-H-9-Borafluorene dimethyl sulfide adduct: a product of a unique ring-contraction reaction and a useful hydroboration reagent

A. Das, A. Hübner, M. Weber, M. Bolte, H. Lerner and M. Wagner, Chem. Commun., 2011, 47, 11339 DOI: 10.1039/C1CC14888E

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