Issue 5, 2012
From the journal:

Chemical Communications

Redox mediation enabled by immobilised centres in the pores of a metal–organic framework grown by liquid phase epitaxy†

André Dragässer,a   Osama Shekhah,b   Olexandra Zybaylo,b   Cai Shen,c   Manfred Buck,c   Christof Wöll*b  and  Derck Schlettwein*a  

* Corresponding authors

a Justus-Liebig-University Gießen, Institute of Applied Physics, Heinrich-Buff-Ring 16, 35392 Gießen, Germany
E-mail: schlettwein@uni-giessen.de

b Karlsruhe Institute of Technology, Institute of Functional Interfaces (IFG), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

c University of St Andrews, EaStCHEM School of Chemistry, North Haugh, St Andrews, UK

Abstract

A layer of a metal–organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

Graphical abstract: Redox mediation enabled by immobilised centres in the pores of a metal–organic framework grown by liquid phase epitaxy

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Article information

DOI
https://doi.org/10.1039/C1CC16580A
Article type
Communication
Submitted
24 Oct 2011
Accepted
16 Nov 2011
First published
17 Nov 2011

Chem. Commun., 2012,48, 663-665

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Redox mediation enabled by immobilised centres in the pores of a metal–organic framework grown by liquid phase epitaxy

A. Dragässer, O. Shekhah, O. Zybaylo, C. Shen, M. Buck, C. Wöll and D. Schlettwein, Chem. Commun., 2012, 48, 663 DOI: 10.1039/C1CC16580A

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