Issue 12, 2011
From the journal:

CrystEngComm

A porous chiral In-MOF with anionic-type diamond network: synthesis, structure and nitrogen gas adsorption†

Liping Wang,a   Tianyou Song,a   Liangliang Huang,a   Jianing Xu,*b   Chao Li,a   Caixia Ji,a   Liang Shana  and  Li Wang*a  

* Corresponding authors

a College of Chemistry, Jilin University, Changchun 130012, Jilin, P. R. China
E-mail: lwang99@jlu.edu.cn
Fax: +86-431-85671974
Tel: + 86-431-85168471

b State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, Jilin, P. R. China
E-mail: xujn@jlu.edu.cn
Fax: +86-431-85671974
Tel: + 86-431-85168471

Abstract

A novel porous chiral In-MOF InH(D-C10H14O4)2 (1) with a left-handed helical channel assembled from D-(+)-camphoric acid (D-H2Cam), has been prepared under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the tetragonal space group P43212 (no. 96) with parameters: a = 13.8954 Å, b = 13.8954 Å, c = 17.7870 Å, V = 3434.4(7) Å 3, Z = 4. The framework feature of compound 1 is characteristic of four-connected anionic-type diamond net with left-handed chiral channel. Moreover, compound 1 exhibits high surface area.

Graphical abstract: A porous chiral In-MOF with anionic-type diamond network: synthesis, structure and nitrogen gas adsorption

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Article information

DOI
https://doi.org/10.1039/C1CE05110E
Article type
Paper
Submitted
21 Jan 2011
Accepted
18 Mar 2011
First published
13 Apr 2011

CrystEngComm, 2011,13, 4005-4009

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A porous chiral In-MOF with anionic-type diamond network: synthesis, structure and nitrogen gas adsorption

L. Wang, T. Song, L. Huang, J. Xu, C. Li, C. Ji, L. Shan and L. Wang, CrystEngComm, 2011, 13, 4005 DOI: 10.1039/C1CE05110E

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