Issue 15, 2011
From the journal:

CrystEngComm

Iron(ii) thio- and selenocyanate coordination networks containing 3,3′-bipyridine†

Christopher J. Adams,*a   Mairi F. Haddow,a   David J. Harding,b   Thomas J. Podestaa  and  Rachel E. Waddingtona  

* Corresponding authors

a School of Chemistry, University of Bristol, Bristol, U.K
E-mail: chcja@bris.ac.uk

b Molecular Technology Research Unit, Department of Chemistry, Walailak University, Thasala, Nakhon Si, Thammarat, Thailand

Abstract

A number of different compounds have been synthesised by reaction of solutions containing Fe(NCE)2 (E = S, Se) with solutions containing 3,3′-bipyridine. When the solvent used is methanol, the products are the monomeric compounds trans-{Fe(NCS)2(3,3′-bipy)2(MeOH)2} 1 or trans-{Fe(NCSe)2(3,3′-bipy)2(MeOH)2} 2, but when acetonitrile is used the layered coordination network {Fe(NCS)2(3,3′-bipy)2} 3 or doubly interpenetrated coordination network {Fe(NCSe)2(3,3′-bipy)2} 4 is formed instead. Using methanol to dissolve the Fe(NCE)2 and CHX3 (X = Cl, Br) to dissolve the 3,3′-bipyridine yields solvated coordination networks of stoichiometry {Fe(NCE)2(3,3′-bipy)2}·2CHX3. The crystal structures of all of these compounds except 4 are presented.

Graphical abstract: Iron(ii) thio- and selenocyanate coordination networks containing 3,3′-bipyridine

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Article information

DOI
https://doi.org/10.1039/C1CE05352C
Article type
Paper
Submitted
23 Mar 2011
Accepted
31 May 2011
First published
10 Jun 2011

CrystEngComm, 2011,13, 4909-4914

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Iron(II) thio- and selenocyanate coordination networks containing 3,3′-bipyridine

C. J. Adams, M. F. Haddow, D. J. Harding, T. J. Podesta and R. E. Waddington, CrystEngComm, 2011, 13, 4909 DOI: 10.1039/C1CE05352C

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