Issue 17, 2011

Solvent-induced 1,3-N,S- vs. 1,5-S,S′-coordination in the NiII complex [Ni{p-Me2NC6H4NHC(S)NP(S)(OiPr)2}2]

Abstract

Reaction of the deprotonated N-thiophosphorylated thiourea p-Me2NC6H4NHC(S)NHP(S)(OiPr)2 (HL) with NiCl2 leads to violet [Ni(L-1,3-N,S)2] or dark violet [Ni(L-1,5-S,S′)2]·(CH3)2C[double bond, length as m-dash]O crystals that were isolated by recrystallization from a mixture of CH2Cl2 or acetone, respectively, and n-hexane.

Graphical abstract: Solvent-induced 1,3-N,S- vs. 1,5-S,S′-coordination in the NiII complex [Ni{p-Me2NC6H4NHC(S)NP(S)(OiPr)2}2]

Supplementary files

Article information

Article type
Communication
Submitted
30 Mar 2011
Accepted
16 Jun 2011
First published
20 Jul 2011

CrystEngComm, 2011,13, 5321-5327

Solvent-induced 1,3-N,S- vs. 1,5-S,S′-coordination in the NiII complex [Ni{p-Me2NC6H4NHC(S)NP(S)(OiPr)2}2]

M. G. Babashkina, D. A. Safin, M. Srebro, P. Kubisiak, M. P. Mitoraj, M. Bolte and Y. Garcia, CrystEngComm, 2011, 13, 5321 DOI: 10.1039/C1CE05387F

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