Issue 20, 2011
From the journal:

CrystEngComm

An unprecedented (3,7)-connected microporous solvatochromic coordination polymer built on a semirigid tripod pyridinium-4-olate ligand†

Jun Zhang,a   Yun-Shan Xue,a   Jing Bai,b   Min Fang,ab   Yi-Zhi Li,a   Hong-Bin Du*a  and  Xiao-Zeng Youa  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China
E-mail: hbdu@nju.edu.cn

b Department of Chemistry, Nanjing Normal University, Nanjing, China

Abstract

A new microporous coordination polymer [Cd4(L)2(BDC)4]·(DMF)3(H2O) (L = 1,1′,1′′-(2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene)tripyridinium-4-olate, BDC = benzene-1,4-dicarboxylic acid) was synthesized, which possesses a (3,7)-connected framework with rectangular tubular open channels, and exhibits permanent porosity and strong photoluminescence with solvatochromic behavior upon excitation.

Graphical abstract: An unprecedented (3,7)-connected microporous solvatochromic coordination polymer built on a semirigid tripod pyridinium-4-olate ligand

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Article information

DOI
https://doi.org/10.1039/C1CE05888F
Article type
Communication
Submitted
17 May 2011
Accepted
15 Jul 2011
First published
18 Aug 2011

CrystEngComm, 2011,13, 6010-6012

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An unprecedented (3,7)-connected microporous solvatochromic coordination polymer built on a semirigid tripod pyridinium-4-olate ligand

J. Zhang, Y. Xue, J. Bai, M. Fang, Y. Li, H. Du and X. You, CrystEngComm, 2011, 13, 6010 DOI: 10.1039/C1CE05888F

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