Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO2 over N2

Dongmei Jiang; Andrew D. Burrows; Karen J. Edler

doi:10.1039/C1CE06274C

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Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO₂ over N₂†

Dongmei Jiang,^a Andrew D. Burrows*^a and Karen J. Edler^a

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^a Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: a.d.burrows@bath.ac.uk
Fax: +44 (0)1225 386231
Tel: +44 (0) 1225 386529

Abstract

Nanoparticles of MIL-101(Cr) have been fabricated using a hydrothermal method for the first time. The particle size can be controlled from 19 (4) nm to 84 (12) nm, by using a monocarboxylic acid as a mediator. These nano MIL-101(Cr) materials exhibit higher selectivities for CO₂ over N₂ than bulk MIL-101(Cr).

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Article information

DOI: https://doi.org/10.1039/C1CE06274C
Article type: Communication
Submitted: 26 Sep 2011
Accepted: 13 Oct 2011
First published: 19 Oct 2011

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CrystEngComm, 2011,13, 6916-6919

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Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO₂ over N₂

D. Jiang, A. D. Burrows and K. J. Edler, CrystEngComm, 2011, 13, 6916 DOI: 10.1039/C1CE06274C

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