Issue 20, 2011

Sizing the Ubbelohde effect: the rotational spectrum of a tert-butylalcohol dimer

Abstract

The H → D isotopic substitution of the hydroxylic hydrogen participating in the O–H⋯O hydrogen bond in the tert-butylalcohol dimer produces an increase of the B and C rotational constants, according to the shrinkage of the O⋯O distance of about 7 mÅ, underlying and sizing the associated Ubbelohde effect.

Graphical abstract: Sizing the Ubbelohde effect: the rotational spectrum of a tert-butylalcohol dimer

Supplementary files

Article information

Article type
Communication
Submitted
24 Jan 2011
Accepted
01 Apr 2011
First published
18 Apr 2011

Phys. Chem. Chem. Phys., 2011,13, 9137-9139

Sizing the Ubbelohde effect: the rotational spectrum of a tert-butylalcohol dimer

S. Tang, I. Majerz and W. Caminati, Phys. Chem. Chem. Phys., 2011, 13, 9137 DOI: 10.1039/C1CP20210C

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