Issue 9, 2011

Divergent reactions on racemic mixtures

Abstract

Methods that furnish enantioenriched products are crucial in modern organic synthesis. An underutilized strategy to arrive at enantioenriched products is to perform divergent reactions on racemic mixtures, where each enantiomer of the starting material reacts with a single chiral reagent to furnish two separable, non-enantiomeric products that are enantioenriched. Stereodivergent, regiodivergent and structurally divergent reactions on racemic mixtures are discussed in this tutorial review.

Graphical abstract: Divergent reactions on racemic mixtures

Article information

Article type
Tutorial Review
Submitted
16 Mar 2011
First published
31 May 2011

Chem. Soc. Rev., 2011,40, 4550-4562

Divergent reactions on racemic mixtures

L. C. Miller and R. Sarpong, Chem. Soc. Rev., 2011, 40, 4550 DOI: 10.1039/C1CS15069C

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