Catalytic        dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds

Torsten Beweries; Sven Hansen; Monty Kessler; Marcus Klahn; Uwe Rosenthal

doi:10.1039/C1DT10366K

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Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds†

Torsten Beweries,^a Sven Hansen,^a Monty Kessler,^a Marcus Klahn^a and Uwe Rosenthal*^a

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* Corresponding authors

^a Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, Rostock, Germany
E-mail: uwe.rosenthal@catalysis.de
Fax: +49 381 128151176
Tel: +49 381 1281176

Abstract

Dehydrogenation of Me₂NH·BH₃ (1) by group 4 metallocene alkyne complexes of the type Cp₂M(L)(η²-Me₃SiC₂SiMe₃) [Cp = η⁵-cyclopentadienyl; M = Ti, no L (2Ti); M = Zr, L = pyridine (2Zr)] and group 4 metal amido complexes of the type M(NMe₂)₄ [M = Ti (8Ti), Zr (8Zr)] is presented.

This article is part of the themed collection: d0 organometallics in catalysis

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Article information

DOI: https://doi.org/10.1039/C1DT10366K
Article type: Communication
Submitted: 23 Mar 2011
Accepted: 04 Apr 2011
First published: 21 Apr 2011

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Dalton Trans., 2011,40, 7689-7692

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Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds

T. Beweries, S. Hansen, M. Kessler, M. Klahn and U. Rosenthal, Dalton Trans., 2011, 40, 7689 DOI: 10.1039/C1DT10366K

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Dalton Transactions