Issue 40, 2011
From the journal:

Dalton Transactions

Coordination of two different metal ions as reason for N-chirality in μ-amide complexes†

Pilar Brandi-Blanco,a   Pablo J. Sanz Miguel*ab  and  Bernhard Lippert*a  

* Corresponding authors

a Fakultät Chemie, Technische Universität Dortmund, Dortmund, Germany
E-mail: bernhard.lippert@tu-dortmund.de
Fax: +49-231-755-3797
Tel: +49-231-755-3840

b Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza – CSIC, Zaragoza, Spain
E-mail: pablo.sanz@unizar.es

Abstract

The primary amine MeNH2, when bonded to PtII, is converted into a methylamide bridge upon coordination of a second, different metal ion (PdII), thereby making the N atom chiral.

Graphical abstract: Coordination of two different metal ions as reason for N-chirality in μ-amide complexes

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Article information

DOI
https://doi.org/10.1039/C1DT10585J
Article type
Communication
Submitted
05 Apr 2011
Accepted
10 Jun 2011
First published
07 Jul 2011

Dalton Trans., 2011,40, 10316-10318

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Coordination of two different metal ions as reason for N-chirality in μ-amide complexes

P. Brandi-Blanco, P. J. S. Miguel and B. Lippert, Dalton Trans., 2011, 40, 10316 DOI: 10.1039/C1DT10585J

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