Issue 45, 2011

Spin-crossover in [Fe(3-bpp)2][BF4]2 in different solvents – A dramatic stabilisation of the low-spin state in water

Abstract

The temperature of spin-crossover in [Fe(3-bpp)2][BF4]2 (3-bpp = 2,6-di{pyrazol-3-yl}pyridine) tends to increase in associating solvents. In particular, T½ shifts to 60–70 K higher temperature in water compared to organic solvents.

Graphical abstract: Spin-crossover in [Fe(3-bpp)2][BF4]2 in different solvents – A dramatic stabilisation of the low-spin state in water

Supplementary files

Article information

Article type
Communication
Submitted
11 Apr 2011
Accepted
06 May 2011
First published
16 May 2011

Dalton Trans., 2011,40, 12021-12024

Spin-crossover in [Fe(3-bpp)2][BF4]2 in different solvents – A dramatic stabilisation of the low-spin state in water

S. A. Barrett, C. A. Kilner and M. A. Halcrow, Dalton Trans., 2011, 40, 12021 DOI: 10.1039/C1DT10620A

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