Issue 34, 2011
From the journal:

Dalton Transactions

Pseudorotaxane-type n-hydrocarbon container. Metallacyclodimer of ionic palladium(ii) complexes containing 1,3-bis(4-pyridyl)tetramethyldisiloxane†

Jungmin Ahn,a   Sung Min Kim,a   Tae Hwan Noha  and  Ok-Sang Jung*a  

* Corresponding authors

a Department of Chemistry, Pusan National University, Pusan, Republic of Korea
E-mail: oksjung@pusan.ac.kr
Fax: (+82) 51-5163522
Tel: (+82) 51-5103240

Abstract

An unusual “pseudorotaxaned n-alkane within a metalla-cyclodimer” system, CnH2n+2@[(Me4en)Pd(L)]2(CF3SO3)4 (n = 5, 6, 7; Me4en = N,N,N′,N′-tetramethylethylenediamine; L = 1,3-bis(4-pyridyl)tetramethyldisiloxane), was constructed. This system is the first pseudorotaxane-type petroleum container achieved via the appropriate size effect.

Graphical abstract: Pseudorotaxane-type n-hydrocarbon container. Metallacyclodimer of ionic palladium(ii) complexes containing 1,3-bis(4-pyridyl)tetramethyldisiloxane

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Article information

DOI
https://doi.org/10.1039/C1DT10980D
Article type
Communication
Submitted
25 May 2011
Accepted
08 Jul 2011
First published
28 Jul 2011

Dalton Trans., 2011,40, 8520-8522

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Pseudorotaxane-type n-hydrocarbon container. Metallacyclodimer of ionic palladium(II) complexes containing 1,3-bis(4-pyridyl)tetramethyldisiloxane

J. Ahn, S. Min Kim, T. Hwan Noh and O. Jung, Dalton Trans., 2011, 40, 8520 DOI: 10.1039/C1DT10980D

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