Dinuclear molybdenum cluster-catalyzed radical addition and polymerization reactions by tuning the redox potential of a quadruple bonded Mo2 core

Hayato Tsurugi; Kohei Yamada; Moumita Majumdar; Yoshitaka Sugino; Akio Hayakawa; Kazushi Mashima

doi:10.1039/C1DT11129A

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Dinuclear molybdenum cluster-catalyzed radical addition and polymerization reactions by tuning the redox potential of a quadruple bonded Mo₂ core†

Hayato Tsurugi,^a Kohei Yamada,^a Moumita Majumdar,^a Yoshitaka Sugino,^a Akio Hayakawa^a and Kazushi Mashima*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Engineering Science, Osaka University, and CREST, JST, Toyonaka, Osaka, Japan
E-mail: mashima@chem.es.osaka-u.ac.jp
Fax: +81-6-6850-6245
Tel: +81-6-6850-6245

Abstract

We developed dinuclear molybdenum cluster-catalyzed radical addition and polymerization reactions by tuning the redox potential of the Mo₂ core. A 2,4,6-triisopropylbenzoate-supported Mo₂ complex acts as a catalyst for radical addition reactions of polyhaloalkanes to 1-alkenes and cyclopentene, while amidinate- and guanidinate-supported Mo₂ clusters are effective catalysts for the radical polymerization reaction of methyl methacrylate.

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Article information

DOI: https://doi.org/10.1039/C1DT11129A
Article type: Communication
Submitted: 16 Jun 2011
Accepted: 18 Jul 2011
First published: 18 Aug 2011

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Dalton Trans., 2011,40, 9358-9361

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Dinuclear molybdenum cluster-catalyzed radical addition and polymerization reactions by tuning the redox potential of a quadruple bonded Mo₂ core

H. Tsurugi, K. Yamada, M. Majumdar, Y. Sugino, A. Hayakawa and K. Mashima, Dalton Trans., 2011, 40, 9358 DOI: 10.1039/C1DT11129A

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