Issue 13, 2012
From the journal:

Dalton Transactions

Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers†

Stefan Spirk,a   Raphael J. F. Berger,a   Christian G. Reuter,a   Rudolf Pietschnigb  and  Norbert W. Mitzel*a  

* Corresponding authors

a University of Bielefeld, Inorganic and Structural Chemistry, Universitätsstraße 25, Bielefeld, Germany
E-mail: mitzel@uni-bielefeld.de
Fax: +495211066026
Tel: +495211066182

b Karl-Franzens-University Graz, Department of Chemistry, Schubertstraße 1, Graz, Austria
E-mail: rudolf.pietschnig@uni-graz.at
Fax: +43316 380 9835
Tel: +433163805287

Abstract

The first gas phase structure of a silanetriol, tert-butylsilane-triol [tBuSi(OH)3], determined by gas electron diffraction (GED), is reported. Quantum chemical calculations have been performed to elucidate potential intermolecular interactions between silanetriol molecules in the gas phase. The results are set into contrast to solid state structures of tBuSi(OH)3 and related compounds.

Graphical abstract: Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers

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Article information

DOI
https://doi.org/10.1039/C1DT11740H
Article type
Communication
Submitted
21 Sep 2011
Accepted
26 Oct 2011
First published
17 Nov 2011

Dalton Trans., 2012,41, 3630-3632

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Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers

S. Spirk, R. J. F. Berger, C. G. Reuter, R. Pietschnig and N. W. Mitzel, Dalton Trans., 2012, 41, 3630 DOI: 10.1039/C1DT11740H

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