Non-precious Co3O4 nano-rod electrocatalyst for oxygenreduction reaction in anion-exchange membranefuelcells

Abstract

We report preparation of carbon-supported Co₃O₄ electrocatalysts with nano-rods and spherical structures by the solvent-mediated morphological control method. The catalytic properties of the prepared catalysts for the oxygen reduction reaction (ORR) in alkaline media are investigated. We show that the ORR catalytic activity of the prepared catalysts is sensitive to the number and activity of surface-exposed Co³⁺ ions that can be tailored by the morphology of cobalt oxides. In particular, we demonstrate that the non-precious Co₃O₄ electrocatalyst with the nano-rod structure (∼12 nm in length and ∼5.1 nm in diameter) prepared in the mixed solvent of water to dimethylformamide ratio of 1 : 1 exhibits a higher current density than a much more expensive palladium-based catalyst does at the low potential region.