Issue 5, 2011
From the journal:

Green Chemistry

Palladium-supported ionic liquidcatalyst (Pd-SH-SILC) immobilized on mercaptopropyl silica gel as a chemoselective, reusable and heterogeneous catalyst for catalytic hydrogenation†

Hisahiro Hagiwara,*a   Tomomi Nakamura,a   Takashi Hoshib  and  Toshio Suzukib  

* Corresponding authors

a Graduate School of Science and Technology, Niigata University, 8050, 2-Nocho, Ikarashi, Nishi-ku, Niigata, Japan
E-mail: hagiwara@gs.niigata-u.ac.jp
Fax: +81-252627368
Tel: +81-252627368

b Faculty of Engineering, Niigata University, 8050, 2-Nocho, Ikarashi, Nishi-ku, Niigata, Japan

Abstract

Palladium acetate was immobilized as Pd-SH-SILC (Pd-supported ionic liquid catalyst) in the pores of amorphous mercaptopropyl silica gel with the aid of an ionic liquid [bmim]BF4. The heterogeneous Pd-SH-SILC was effective for catalytic hydrogenation of a variety of olefins at atmospheric pressure and room temperature. It withstood recycling up to 10 times by decantation.

Graphical abstract: Palladium-supported ionic liquid catalyst (Pd-SH-SILC) immobilized on mercaptopropyl silica gel as a chemoselective, reusable and heterogeneous catalyst for catalytic hydrogenation

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Article information

DOI
https://doi.org/10.1039/C1GC15217C
Article type
Communication
Submitted
28 Feb 2011
Accepted
15 Mar 2011
First published
30 Mar 2011

Green Chem., 2011,13, 1133-1137

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Palladium-supported ionic liquid catalyst (Pd-SH-SILC) immobilized on mercaptopropyl silica gel as a chemoselective, reusable and heterogeneous catalyst for catalytic hydrogenation

H. Hagiwara, T. Nakamura, T. Hoshi and T. Suzuki, Green Chem., 2011, 13, 1133 DOI: 10.1039/C1GC15217C

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