Issue 40, 2011
From the journal:

Journal of Materials Chemistry

Vapochromic and vapoluminescent response of materials based on platinum(ii) complexes intercalated into layered zirconium phosphate†

Eladio J. Rivera,a   Cindy Barbosa,a   Rafael Torres,a   Levi Grove,b   Stephen Taylor,b   William B. Connick,b   Abraham Clearfieldc  and  Jorge L. Colón*a  

* Corresponding authors

a Department of Chemistry, University of Puerto Rico, P.O. Box 23346, Río Piedras, P.R, USA
E-mail: jlcolon@uprrp.edu.
Fax: (+787) 756-8242
Tel: (+787) 764-0000, ext. 3220

b Department of Chemistry, University of Cincinnati, P.O. Box 210172, Cincinnati, Ohio, USA

c Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX, USA

Abstract

Novel materials based on platinum(II) complexes incorporated into zirconium phosphate (ZrP) frameworks exhibit rapid and reversible vapochromic/vapoluminescent response upon exposure to volatile organic compounds (VOCs). The pattern response is distinctly different than that of salts of the platinum complexes. These results suggest that the microenvironment of the ZrP can modulate the properties of vapochromic compounds.

Graphical abstract: Vapochromic and vapoluminescent response of materials based on platinum(ii) complexes intercalated into layered zirconium phosphate

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Article information

DOI
https://doi.org/10.1039/C1JM12053K
Article type
Communication
Submitted
10 May 2011
Accepted
22 Aug 2011
First published
07 Sep 2011

J. Mater. Chem., 2011,21, 15899-15902

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Vapochromic and vapoluminescent response of materials based on platinum(II) complexes intercalated into layered zirconium phosphate

E. J. Rivera, C. Barbosa, R. Torres, L. Grove, S. Taylor, W. B. Connick, A. Clearfield and J. L. Colón, J. Mater. Chem., 2011, 21, 15899 DOI: 10.1039/C1JM12053K

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