Issue 2, 2012

Novel organic–inorganic hybrid ferroelectric: bis(imidazolium) pentachloroantimonate(iii), (C3N2H5)2SbCl5

Abstract

Electric permittivity, reaching ca. 4800 units at Tc, of the first haloantimonate(III) ferroelectric with R2MX5 composition characterized by unprecedented SbCl5 chains of cis-connected octahedra results from the mixed ‘order–disorder’ and ‘displacive’ mechanism of the phase transition.

Graphical abstract: Novel organic–inorganic hybrid ferroelectric: bis(imidazolium) pentachloroantimonate(iii), (C3N2H5)2SbCl5

Supplementary files

Article information

Article type
Communication
Submitted
28 Jul 2011
Accepted
05 Nov 2011
First published
23 Nov 2011

J. Mater. Chem., 2012,22, 333-336

Novel organic–inorganic hybrid ferroelectric: bis(imidazolium) pentachloroantimonate(III), (C3N2H5)2SbCl5

A. Piecha, A. Białońska and R. Jakubas, J. Mater. Chem., 2012, 22, 333 DOI: 10.1039/C1JM13597J

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