Issue 1, 2012
From the journal:

Polymer Chemistry

Aqueous RAFT/MADIXpolymerisation of N-vinyl pyrrolidone at ambient temperature†

Aymeric Guinaudeau,a   Stéphane Mazières,a   D. James Wilsonb  and  Mathias Destarac*a  

* Corresponding authors

a UniversicPaul Sabatier, Laboratoire Hétérochimie Fondamentale et Appliquée, UMR-CNRS 5069, Bât 2R1, 118 route de Narbonne, Toulouse Cedex 9, France
E-mail: destarac@chimie.ups-tlse.fr
Fax: +33 (0)5 6155 8204
Tel: +33 (0)5 6155 6354

b Rhodia Opérations, Centre de Recherches et Technologies d'Aubervilliers, 52 rue de la Haie Coq, Aubervilliers Cedex, France

Abstract

The RAFT/MADIXpolymerisation of N-vinyl pyrrolidone was successfully carried out in homogeneous water medium at 25 °C using the tert-butyl hydroperoxide/ascorbic acidredoxinitiator. The controlled character of the polymerisation was confirmed by MALDI-TOF mass spectrometry, SEC and NMR analyses. This finding paves the way for the preparation of novel all-hydrophilic complex copolymer architectures based on poly(N-vinyl pyrrolidone).

Graphical abstract: Aqueous RAFT/MADIXpolymerisation of N-vinyl pyrrolidone at ambient temperature

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Article information

DOI
https://doi.org/10.1039/C1PY00373A
Article type
Communication
Submitted
23 Aug 2011
Accepted
25 Sep 2011
First published
14 Oct 2011

Polym. Chem., 2012,3, 81-84

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Aqueous RAFT/MADIXpolymerisation of N-vinyl pyrrolidone at ambient temperature

A. Guinaudeau, S. Mazières, D. J. Wilson and M. Destarac, Polym. Chem., 2012, 3, 81 DOI: 10.1039/C1PY00373A

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