Issue 7, 2011

Symmetry related [DyIII6MnIII12] cores with different magnetic anisotropies

Abstract

Two heterometallic [DyIII6MnIII12] clusters comprising of the same [MnIII8O13] fragment, four isolated MnIII ions and two linear [DyIII3] units have been synthesised. Except for the same composition, the main difference of these two cores lies in the coordination environment and the orientations of the linear [DyIII3] units. This difference leads to an alternation in the symmetry of the two cores that significantly modulates their magnetic properties including ground spin state and slow relaxation behavior.

Graphical abstract: Symmetry related [DyIII6MnIII12] cores with different magnetic anisotropies

Supplementary files

Article information

Article type
Edge Article
Submitted
16 Feb 2011
Accepted
23 Mar 2011
First published
19 Apr 2011

Chem. Sci., 2011,2, 1268-1272

Symmetry related [DyIII6MnIII12] cores with different magnetic anisotropies

J. Liu, F. Guo, Z. Meng, Y. Zheng, J. Leng, M. Tong, L. Ungur, L. F. Chibotaru, K. J. Heroux and D. N. Hendrickson, Chem. Sci., 2011, 2, 1268 DOI: 10.1039/C1SC00166C

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