Issue 9, 2011

Band gap engineering in fluorescent conjugated microporous polymers

Abstract

We report here the synthesis of conjugated microporous polymers (CMPs) based on pyrene building units. The networks are both microporous and highly luminescent. The emission colour and resulting band gap can be fine tuned by introducing different comonomers and by varying the monomer distribution (statistical versus alternating). These materials might find applications in organic electronics, photocatalysis, optoelectronics, or in sensing technologies.

Graphical abstract: Band gap engineering in fluorescent conjugated microporous polymers

Supplementary files

Article information

Article type
Edge Article
Submitted
26 May 2011
Accepted
20 Jun 2011
First published
07 Jul 2011

Chem. Sci., 2011,2, 1777-1781

Band gap engineering in fluorescent conjugated microporous polymers

J. Jiang, A. Trewin, D. J. Adams and A. I. Cooper, Chem. Sci., 2011, 2, 1777 DOI: 10.1039/C1SC00329A

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