SCHEDULED MAINTENANCE
The equilibration of the two ethylenic carbons and the stereospecificity observed in unimolecular reactions of β-arylthiovinyl sulphonates (I) are explained by the intermediacy of a thiirenium cation (III).
G. Capozzi, G. Melloni, G. Modena and U. Tonellato, J. Chem. Soc. D, 1969, 1520 DOI: 10.1039/C29690001520
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