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Aqueous dimethylformamide (DMF) solutions containing hydroxide ion are unstable, formate ion and dimethylamine being produced fairly rapidly even under mild conditions, with a maximum rate constant at ca. 30 mole% DMF.
E. Buncel and E. A. Symons, J. Chem. Soc. D, 1970, 164 DOI: 10.1039/C29700000164
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