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The free radical addition of SF5Cl to trifluoroethylene in the gas phase yields both adducts (a) SF5CHFCF2Cl and (b) SF5CF2CHFCl, the ratio [a]/[b] depending not only on temperature but also on the absolute concentration of SF5Cl: these observations can be accounted for in terms of reversible addition of ˙SF5 radicals.
H. W. Sidebottom, J. M. Tedder and J. C. Walton, J. Chem. Soc. D, 1970, 253 DOI: 10.1039/C29700000253
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