Issue 28, 2012
From the journal:

Chemical Communications

Chemical communication: conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains†‡

Thomas Boddaert,a   Jordi Solà,a   Madeleine Helliwella  and  Jonathan Clayden*a  

* Corresponding authors

a School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK
E-mail: clayden@man.ac.uk

Abstract

1H NMR studies quantify the abilities of achiral amino acids to communicate a left-handed screw-sense preference from one helical Aib4 domain to another: certain quaternary amino acids (e.g. Ac6c) act as effective conductors of conformational preference while others (e.g. diphenylglycine) acts as insulators.

Graphical abstract: Chemical communication: conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

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Article information

DOI
https://doi.org/10.1039/C2CC00060A
Article type
Communication
Submitted
04 Jan 2012
Accepted
30 Jan 2012
First published
31 Jan 2012

Chem. Commun., 2012,48, 3397-3399

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Chemical communication: conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

T. Boddaert, J. Solà, M. Helliwell and J. Clayden, Chem. Commun., 2012, 48, 3397 DOI: 10.1039/C2CC00060A

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