Issue 24, 2012

Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(iii) double-decker SMMs

Abstract

Correlation between molecular structures and slow relaxation of magnetization of three mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-deckers clearly reveals the effect of the sandwich-type molecular structure, in particular the twist angle, on the quantum tunneling (QT) at zero dc field of these complexes, providing the first direct evidence to the theoretical inference.

Graphical abstract: Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(iii) double-decker SMMs

Supplementary files

Article information

Article type
Communication
Submitted
21 Oct 2011
Accepted
17 Jan 2012
First published
18 Jan 2012

Chem. Commun., 2012,48, 2973-2975

Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-decker SMMs

H. Wang, K. Wang, J. Tao and J. Jiang, Chem. Commun., 2012, 48, 2973 DOI: 10.1039/C2CC16543K

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