Issue 16, 2012

Palladium-catalyzed allylic C–H amination of alkenes with N-fluorodibenzenesulfonimide: water plays an important role

Abstract

A new palladium-catalyzed highly regioselective allylic C–H amination of alkenes with NFSI in the presence of a catalytic amount of water was developed and successfully expanded to Selectfluor-mediated palladium-catalyzed aminations of alkenes with N-tosylcarbamates in water at room temperature.

Graphical abstract: Palladium-catalyzed allylic C–H amination of alkenes with N-fluorodibenzenesulfonimide: water plays an important role

Supplementary files

Article information

Article type
Communication
Submitted
30 Oct 2011
Accepted
22 Dec 2011
First published
17 Jan 2012

Chem. Commun., 2012,48, 2246-2248

Palladium-catalyzed allylic C–H amination of alkenes with N-fluorodibenzenesulfonimide: water plays an important role

T. Xiong, Y. Li, L. Mao, Q. Zhang and Q. Zhang, Chem. Commun., 2012, 48, 2246 DOI: 10.1039/C2CC16720D

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