Issue 8, 2012
From the journal:

Chemical Communications

A pyrovanadate-templated silver(i)–ethynide cluster circumscribed by macrocyclic polyoxovanadate(v)†

Yun-Peng Xiea  and  Thomas C. W. Mak*ab  

* Corresponding authors

a Department of Chemistry and Center of Novel Functional Molecules, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, People's Republic of China
E-mail: tcwmak@cuhk.edu.hk

b Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia, (Honorary Chair Professor)

Abstract

In the giant mixed-metal silver(I)–ethynide cluster compound [Bz(Et)3N+]8[(Et)4N+]2[(V2O7)2@Ag44(C[triple bond, length as m-dash]CtBu)14@(V32O96)], the cyclic polyoxovanadate {V32O96} located at a [4 with combining macron] site takes a contorted configuration to wrap around an inner Ag44 cluster that in turn encapsulates a pair of pyrovanadate templates.

Graphical abstract: A pyrovanadate-templated silver(i)–ethynide cluster circumscribed by macrocyclic polyoxovanadate(v)

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Article information

DOI
https://doi.org/10.1039/C2CC16756E
Article type
Communication
Submitted
01 Nov 2011
Accepted
01 Dec 2011
First published
02 Dec 2011

Chem. Commun., 2012,48, 1123-1125

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A pyrovanadate-templated silver(I)–ethynide cluster circumscribed by macrocyclic polyoxovanadate(V)

Y. Xie and T. C. W. Mak, Chem. Commun., 2012, 48, 1123 DOI: 10.1039/C2CC16756E

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