Issue 25, 2012

Monofunctionalised cucurbit[6]uril synthesis using imidazolium host–guest complexation

Abstract

Monohydroxylated cucurbit[6]uril was prepared for the first time through the controlled oxidation of CB[6] in the presence of a tailor-made bisimidazolium guest, as verified by 1H NMR, ESI-MS and X-ray crystallography. Further chemical modification of monohydroxylated CB[6] was also readily achieved.

Graphical abstract: Monofunctionalised cucurbit[6]uril synthesis using imidazolium host–guest complexation

Supplementary files

Article information

Article type
Communication
Submitted
28 Nov 2011
Accepted
19 Jan 2012
First published
20 Jan 2012

Chem. Commun., 2012,48, 3070-3072

Monofunctionalised cucurbit[6]uril synthesis using imidazolium host–guest complexation

N. Zhao, G. O. Lloyd and O. A. Scherman, Chem. Commun., 2012, 48, 3070 DOI: 10.1039/C2CC17433B

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