Issue 23, 2012
From the journal:

Chemical Communications

Dehydrogenative Heck coupling of biologically relevant N-heteroarenes with alkenes: discovery of fluorescent core frameworks†

Yumin Huang,a   Feijie Song,a   Zhen Wang,a   Peihua Xi,a   Ningjie Wu,a   Zhigang Wang,a   Jingbo Lana  and  Jingsong You*a  

* Corresponding authors

a Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, PR China
E-mail: jsyou@scu.edu.cn
Fax: +86 28-85412203

Abstract

A Pd/Cu-catalyzed dehydrogenative Heck coupling is established that allows direct alkenylation of various biologically relevant N-heteroarenes with alkenes. The resulting π-extended alkenylated N-heteroarenes exhibit interesting fluorescent properties and have proven to be potentially useful fluorescent probes for bioimaging.

Graphical abstract: Dehydrogenative Heck coupling of biologically relevant N-heteroarenes with alkenes: discovery of fluorescent core frameworks

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Article information

DOI
https://doi.org/10.1039/C2CC17557F
Article type
Communication
Submitted
03 Dec 2011
Accepted
18 Jan 2012
First published
18 Jan 2012

Chem. Commun., 2012,48, 2864-2866

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Dehydrogenative Heck coupling of biologically relevant N-heteroarenes with alkenes: discovery of fluorescent core frameworks

Y. Huang, F. Song, Z. Wang, P. Xi, N. Wu, Z. Wang, J. Lan and J. You, Chem. Commun., 2012, 48, 2864 DOI: 10.1039/C2CC17557F

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