Issue 50, 2012

Rational design of a phthalocyanine–perylenediimide dyad with a long-lived charge-separated state

Abstract

A new ZnPc–PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs.

Graphical abstract: Rational design of a phthalocyanine–perylenediimide dyad with a long-lived charge-separated state

Supplementary files

Article information

Article type
Communication
Submitted
14 Feb 2012
Accepted
02 May 2012
First published
04 May 2012

Chem. Commun., 2012,48, 6241-6243

Rational design of a phthalocyanine–perylenediimide dyad with a long-lived charge-separated state

V. M. Blas-Ferrando, J. Ortiz, L. Bouissane, K. Ohkubo, S. Fukuzumi, F. Fernández-Lázaro and Á. Sastre-Santos, Chem. Commun., 2012, 48, 6241 DOI: 10.1039/C2CC31087B

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