Issue 43, 2012
From the journal:

Chemical Communications

Programmable self-assembly of homo- or hetero-metallomacrocycles using 4-(1H-pyrazolyl-4-yl)pyridine†

Jin Tong,a   Shu-Yan Yu*a  and  Hui Li*b  

* Corresponding authors

a Laboratory for Self-Assembly Chemistry, Department of Chemistry, Renmin University of China, Beijing 100872, China
E-mail: yusy@ruc.edu.cn
Fax: +86-10-62516614
Tel: +86-10-62516614

b School of Material Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
E-mail: lihui@ecust.edu.cn

Abstract

The dimetallic [M2(bpy)2(NO3)2](NO3)2 moieties (M = Pd(II) or Pt(II)) react preferentially at the pyrazolyl end of the pyridyl-pyrazole ligand, giving rise to dimetallic corners. Subsequently, the dimetallic corner building blocks featuring two pyridine donors are coordinated by monometallic [M(bpy)(NO3)2] moieties (M = Pd(II) or Pt(II)) to form homo- or hetero-metallomacrocycles.

Graphical abstract: Programmable self-assembly of homo- or hetero-metallomacrocycles using 4-(1H-pyrazolyl-4-yl)pyridine

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Article information

DOI
https://doi.org/10.1039/C2CC31234D
Article type
Communication
Submitted
18 Feb 2012
Accepted
23 Mar 2012
First published
27 Mar 2012

Chem. Commun., 2012,48, 5343-5345

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Programmable self-assembly of homo- or hetero-metallomacrocycles using 4-(1H-pyrazolyl-4-yl)pyridine

J. Tong, S. Yu and H. Li, Chem. Commun., 2012, 48, 5343 DOI: 10.1039/C2CC31234D

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