Issue 38, 2012
From the journal:

Chemical Communications

Enantioselective organocatalytic reductive amination of aliphatic ketones by benzothiazoline as hydrogen donor†

Kodai Saitoa  and  Takahiko Akiyama*a  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Gakushuin University, Mejiro, Toshima-ku, Tokyo 171-8558, Japan
E-mail: takahiko.akiyama@gakushuin.ac.jp
Fax: +81-3-5992-1029
Tel: +81-3-3986-0221

Abstract

The chiral phosphoric acid-catalyzed enantioselective reductive amination of aliphatic ketones with aromatic amines was successfully achieved by the use of benzothiazoline as the hydrogen donor. Corresponding chiral aliphatic amines were obtained with excellent enantioselectivities.

Graphical abstract: Enantioselective organocatalytic reductive amination of aliphatic ketones by benzothiazoline as hydrogen donor

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Article information

DOI
https://doi.org/10.1039/C2CC31486J
Article type
Communication
Submitted
28 Feb 2012
Accepted
17 Mar 2012
First published
19 Mar 2012

Chem. Commun., 2012,48, 4573-4575

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Enantioselective organocatalytic reductive amination of aliphatic ketones by benzothiazoline as hydrogen donor

K. Saito and T. Akiyama, Chem. Commun., 2012, 48, 4573 DOI: 10.1039/C2CC31486J

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