Issue 55, 2012

An elegant access to formation and vaporization enthalpies of ionic liquids by indirect DSC experiment and “in silico” calculations

Abstract

We used DSC for determination of the reaction enthalpy of the synthesis of the ionic liquid [C4mim][Cl]. A combination of DSC and quantum chemical calculations presents a new, indirect way to study thermodynamics of ionic liquids. The new procedure was validated with two direct experimental measurements and MD simulations.

Graphical abstract: An elegant access to formation and vaporization enthalpies of ionic liquids by indirect DSC experiment and “in silico” calculations

Supplementary files

Article information

Article type
Communication
Submitted
28 Feb 2012
Accepted
15 May 2012
First published
16 May 2012

Chem. Commun., 2012,48, 6915-6917

An elegant access to formation and vaporization enthalpies of ionic liquids by indirect DSC experiment and “in silico” calculations

S. P. Verevkin, D. H. Zaitsau, V. N. Emel'yanenko, C. Schick, S. Jayaraman and E. J. Maginn, Chem. Commun., 2012, 48, 6915 DOI: 10.1039/C2CC31504A

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