Issue 64, 2012

Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes

Abstract

The regio- and diastereoselective silaboration of aromatic alkenes with a silylboron compound proceeds in the presence of a catalytic amount of potassium tert-butoxide, providing a complementary method to the corresponding transition metal-catalyzed reactions.

Graphical abstract: Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes

Supplementary files

Article information

Article type
Communication
Submitted
19 Apr 2012
Accepted
18 Jun 2012
First published
21 Jun 2012

Chem. Commun., 2012,48, 8006-8008

Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes

H. Ito, Y. Horita and E. Yamamoto, Chem. Commun., 2012, 48, 8006 DOI: 10.1039/C2CC32778C

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