Issue 58, 2012
From the journal:

Chemical Communications

Cyclometallated gold(iii) hydroxides as versatile synthons for Au–N, Au–C complexes and luminescent compounds†

Dragoş-Adrian Roşca,a   Dan A. Smitha  and  Manfred Bochmann*a  

* Corresponding authors

a Wolfson Materials and Catalysis Centre, School of Chemistry, University of East Anglia, Norwich, UK
E-mail: m.bochmann@uea.ac.uk
Fax: +44 (0)016035 92044

Abstract

The gold(III) hydroxide κ3-(C∧N∧C)*Au(OH) reacts with C–H and N–H compounds and arylboronic acids to produce a range of perfluoroaryls, N-heterocyclic and alkynyl compounds in high yields; some of which show unexpectedly strong modulation of their photoluminescence from yellow to blue [(C∧N∧C)* = 2,6-(C6H3But)2pyridine].

Graphical abstract: Cyclometallated gold(iii) hydroxides as versatile synthons for Au–N, Au–C complexes and luminescent compounds

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Article information

DOI
https://doi.org/10.1039/C2CC33104G
Article type
Communication
Submitted
30 Apr 2012
Accepted
22 May 2012
First published
23 May 2012

Chem. Commun., 2012,48, 7247-7249

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Cyclometallated gold(III) hydroxides as versatile synthons for Au–N, Au–C complexes and luminescent compounds

D. Roşca, D. A. Smith and M. Bochmann, Chem. Commun., 2012, 48, 7247 DOI: 10.1039/C2CC33104G

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