Issue 66, 2012

CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine

Abstract

Photocatalytic CO2 reduction has been studied for two dyads with porphyrin covalently attached to rhenium tricarbonyl bipyridine moieties, and on separate components consisting of [Re(CO)3(Picoline)Bpy]+ and either zinc porphyrin or zinc chlorin. TONs decrease in the order: zinc porphyrin + Re > long spacer dyad > zinc chlorin + Re > short spacer dyad.

Graphical abstract: CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine

Supplementary files

Article information

Article type
Communication
Submitted
08 May 2012
Accepted
18 Jun 2012
First published
19 Jun 2012

Chem. Commun., 2012,48, 8189-8191

CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine

C. D. Windle, M. V. Câmpian, Anne-K. Duhme-Klair, E. A. Gibson, R. N. Perutz and J. Schneider, Chem. Commun., 2012, 48, 8189 DOI: 10.1039/C2CC33308B

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